Basically, KNOPPIX is bootable cd with Debian, KDE, and TONS of other crap. It boots up, autodetects hardware, and loads up KDE. All without using a hard drive. Perfect for newbs wanting to check out Linux without breaking their Windows install.
http://www.knopper.net/knoppix/index-en.html
Now what's really cool, is that it can also be used as an automated Linux install tool.
http://www.freenet.org.nz/misc/knoppix-install.html
This install is simple enough, that total beginers should be able to do it without incident.
I just used Partition Magic / Boot Magic on my machine, ran through the KNOPPIX install, and now I've got a dual boot XP / Linux machine. It took a little time to adjust the partitions and such, but other then that, it was a painless install. And everything worked without incident. =)